<item WBfacePracticeItem>
/ 1 = "./W000-B100 L.jpg"
/ 2 = "./W100-B000 L.jpg"
/ 3 = "./W000-B100 R.jpg"
/ 4 = "./W100-B000 R.jpg"
</item>
You should try to avoid spaces in filenames as well as the path prefix as clearly indicated by the resulting invalid URL in the error message:
"Unable to load the picture 'http://www.millisecond.com/myaccount/scripts/eknowles/RaceCat/./W020-B080 R.jpg'. Verify the file is of a supported image format."