Hmm, you're probably just missing the fact that Inquisit's '/ stimulusframes' and '/ stimulustimes' attributes are sensitive to the ordering of elements. Suppose you have defined <picture bunny> and <shape border>. The following <trial> element will draw the shape on top of the picture
<trial shapeontop>
/ stimulusframes = [1=bunny, border]
[...]
</trial>
while defining
<trial picontop>
/ stimulusframes = [1=border, bunny]
[...]
</trial>
will draw the picture on top of the shape (which is what you want). Please see the attached files for further reference.
Best wishes from a fellow Inquisit user,
~Dave